ISSN

0974-4150 (Online)
0974-4169 (Print)


Author(s): Khadra Mokadem, Belfar Mohemed Lakhdar, Kaniki Tumba, Abdulqader Saad Abed, Mourad Korichi

Email(s): mo2kadem@gmail.com

DOI: 10.52711/0974-4150.2022.00071   

Address: Khadra Mokadem1*, Belfar Mohemed Lakhdar1, Kaniki Tumba2, Abdulqader Saad Abed3, Mourad Korichi1
1Kasdi Merbah Ouargla University, B.P. 511, 30000, Ouargla, Algeria.
2Department of Chemical Engineering, Mangosuthu University of Technology, Durban, South Africa.
3Ministry of water Resources, State commission on Operation of Irrigation and Drainage projects, Water Resources, El Anbar, Iraq.
*Corresponding Author

Published In:   Volume - 15,      Issue - 6,     Year - 2022


ABSTRACT:
A linear model based on group-interaction contributions is proposed for the estimation of the freezing temperature (Tf) of ionic liquids (ILs). This property is important for modelling solid-liquid equilibrium and selecting ionic liquids as reaction media among other things. A database of 66 experimental freezing points different ionic liquids was used to obtain all interaction contribution parameters and model constants. The database included various classes of ionic liquids and a wide range of cation and anion groups., with an average absolute relative deviation of 4,09% and a correlation coefficient of 0,93.


Cite this article:
Khadra Mokadem, Belfar Mohemed Lakhdar, Kaniki Tumba, Abdulqader Saad Abed, Mourad Korichi. A Simple Group-Interaction Contribution Method for the Prediction of the Freezing Point of Ionic Liquids. Asian Journal of Research in Chemistry. 2022; 15(6):404-8. doi: 10.52711/0974-4150.2022.00071

Cite(Electronic):
Khadra Mokadem, Belfar Mohemed Lakhdar, Kaniki Tumba, Abdulqader Saad Abed, Mourad Korichi. A Simple Group-Interaction Contribution Method for the Prediction of the Freezing Point of Ionic Liquids. Asian Journal of Research in Chemistry. 2022; 15(6):404-8. doi: 10.52711/0974-4150.2022.00071   Available on: https://www.ajrconline.org/AbstractView.aspx?PID=2022-15-6-3


REFERENCES:
1.    Villanueva J. S. M. Thermal Properties of Pure Ionic liquids, in: A.P.D.L.R.a.F.J.H. Fernandez (Ed.) Ionic Liquids in Separation Technology, Elsevier. 2014; ISBN: 9780444632623
2.    Plechkova N. V. Seddon K.R., Applications of ionic liquids in the chemical industry, Chemical Society Reviews. 2008; 37, 123-150.doi.org/10.1039/B006677J
3.    Fox D. M. Gilman J.W. Morgan A.B. Shields J.R. Maupin P.H., Lyon R.E. De Long H.C. Trulove P.C. Flammability and thermal analysis characterization of imidazolium-based ionic liquids, Industrial & Engineering Chemistry Research. 2008; 47:6327-6332. DOI10.1021/ie800665u
4.    Rogers R. D. Seddon K.R. Ionic liquids--solvents of the future?, Science.2003;302:792-793.DOI: 10.1126/science.1090313
5.    Trulove P. C. Mantz R.A. Electrochemical properties of ionic liquids, in, Wiley-VCH: Morlenbach., 2003. ISBN 3-527-30612-9
6.    Dupont J. On the solid, liquid and solution structural organization of imidazolium ionic liquids, Journal of the Brazilian Chemical Society.2004;15:341-350. https://doi.org/10.1590/S0103-50532004000300002
7.    Schröder U. Wadhawan J. D. Compton R. G. Marken, F. Suarez P. A. Z. Consorti C. S Consorti. F. Roberto de Souzab and Dupont J. Water-induced accelerated ion diffusion: voltammetric studies in 1-methyl-3-[2,6-(S)-dimethylocten-2-yl]imidazolium tetrafluoroborate, 1-butyl-3-methylimidazolium tetrafluoroborate and hexafluorophosphate ionic liquids. J. New J. Chem. 2000;24:1009–1015.DOIhttps://doi.org/10.1039/B007172M
8.    Marrero‐MorejónJ. GaniR.Group-contribution based estimation of pure component properties, Fluid Phase Equilibria. 2001;183:183-208.DOI:10.1016/S0378-3812(01)00431-9
9.    Pardillo-Fontdevila E. González-Rubio R. A group-interaction contribution approach. A new strategy for the estimation of physico-chemical properties of branched isomers, Chemical Engineering Communications. 1998; 163:245-254.
10.    Zhang S. Sun N., He X. Lu X. Zhang X. Physical properties of ionic liquids: database and evaluation, Journal of physical and chemical reference data.. 2006. 35:1475-1517. https://doi.org/10.1063/1.2204959
11.    S. Zhang, X. Lu, X. Li, Q. Zhou, X. Zhang, S. Li Ionic Liquids: Physicochemical Properties, 1st Edition, Elsevier Science.2009.
12.    Lazzús J. A. A Group Contribution Method For Predicting The Freezing Point Of Ionic Liquids, Periodica Polytechnica Chemical Engineering. 2016; Doi: 10.3311/Ppce.9082. DOI: 10.3311/PPce.9082
13.    Constantinou L. Gani R. New group contribution method for estimating properties of pure compounds, AIChE Journal. 1994 ;40,1697-1710. DOI:10.1002/AIC.690401011
14.    Marrero‐Morejón J. Pardillo‐Fontdevila E. Estimation of pure compound properties using group‐interaction contributions, AIChE journal.,1999 ;45: 615-621. doi.org/10.1002/aic.690450318
15.    Mokadem K. Korichi M. Tumba K. A new group-interaction contribution method to predict the thermal decomposition temperature of ionic liquids, Original Research Article, Chemometrics and Intelligent Laboratory Systems.2016; 157:189-195.
16.    Mokadem K. Korichi M. Group - Interaction Contribution Approach for Prediction of Electrochemical Properties of Ionic Liquids, Computer Aided Chemical Engineerin. 2016;38:451-456. DOI: 10.1016/j.fluid.2020.112462


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