Asian Journal of Research in Chemistry

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0974-4150 (Online)
0974-4169 (Print)


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Oxidative Degradtion and Associated Complexation of Ethylacetoacetate by Cr (VI) Based Oxidant

Author(s): K. Akhtar, R. Ranjan, M. Alam

Email(s): rajeevran7@yahoo.com

DOI: Not Available

Address: K. Akhtar1, R. Ranjan1* and M. Alam2
1PG Department of Chemistry, Ranchi College, Ranchi-834008
2University Department of Chemistry, Ranchi University, Ranchi-834008
*Corresponding Author

Published In:   Volume - 5,      Issue - 2,     Year - 2012

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ABSTRACT:
The present paper investigates the action of di-tertiary butyl chromate (TBC) - a Cr(VI) based oxidant - on ethylacetoacetate with following aims: (a) Whether degradation occurs along with oxidation? (b) Whether Cr in reduced state enters into complexation with the oxidised fragments or with the unreacted substrate itself? (c) Whether the oxidation is selective i.e., does arresting the reaction at different stages (by taking different substrate: TBC molar ratios) result into same product or not.


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Cite this article:
K. Akhtar, R. Ranjan, M. Alam. Oxidative Degradtion and Associated Complexation of Ethylacetoacetate by Cr (VI) Based Oxidant. Asian J. Research Chem. 5(2): February 2012; Page 191-192.

Cite(Electronic):
K. Akhtar, R. Ranjan, M. Alam. Oxidative Degradtion and Associated Complexation of Ethylacetoacetate by Cr (VI) Based Oxidant. Asian J. Research Chem. 5(2): February 2012; Page 191-192.   Available on: https://www.ajrconline.org/AbstractView.aspx?PID=2012-5-2-6


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Asian Journal of Research in Chemistry (AJRC) (ISSN: print-0974-4169, Online-0974-4150) is an international, peer-reviewed journal devoted to pure and applied chemistry. AJRC publishes Original Research Articles, Short Communications, Review Articles in all aspects of chemistry. Topics covered including the traditional areas of analytical, inorganic, organic, biochemistry, forensic, physical-theoretical chemistry as well as newer interdisciplinary areas such as agriculture, materials science, computational, medicine, spectroscopy, polymers, supramolecular, surface, chemical physics, biological, medicinal/ drugs, environmental and pharmaceutical chemistry.
The journal is published quarterly every year in last week of March, June, September and December. From January 2011, is monthly and shall be published every year in last week of Month.    
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