Asian Journal of Research in Chemistry

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0974-4150 (Online)
0974-4169 (Print)


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Kinetics and Mechanism of Micelle-Catalysed Oxidation of DL-Alanine and Glycine by Chloromine-T

Author(s): Farhat Hasan Khan, Mahboob Alam

Email(s): mahboobchem@gmail.com

DOI: Not Available

Address: Farhat Hasan Khan and Mahboob Alam*
Department of Chemistry, Aligarh Muslim University, Aligarh -2020 02, India
*Corresponding Author

Published In:   Volume - 4,      Issue - 3,     Year - 2011

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ABSTRACT:
The kinetics of oxidation of DL-alanine by chloramine-T(CAT) in the absence of any surfactant has been studied and compared with the kinetics parameters observed in the presence of anionic micelles of sodium dodecyl sulfate (SDS) and cationic micelles of cetyl pyridinium chloride (CPC). The observed rate law in respect of [alanine] and [oxidant] is given as: d[CAT] ? = k / [alanine] [CAT] dt Where k / is a complex function of hydrogen ion concentration as well as surfactant concentration. In the presence of CPC, the kinetic features of decarboxylation of DL-alanine are different from those observed in the case of glycine.


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Cite this article:
Farhat Hasan Khan, Mahboob Alam. Kinetics and Mechanism of Micelle-Catalysed Oxidation of DL-Alanine and Glycine by Chloromine-T. Asian J. Research Chem. 4(3): March 2011; Page 468-480.

Cite(Electronic):
Farhat Hasan Khan, Mahboob Alam. Kinetics and Mechanism of Micelle-Catalysed Oxidation of DL-Alanine and Glycine by Chloromine-T. Asian J. Research Chem. 4(3): March 2011; Page 468-480.   Available on: https://www.ajrconline.org/AbstractView.aspx?PID=2011-4-3-29


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Asian Journal of Research in Chemistry (AJRC) (ISSN: print-0974-4169, Online-0974-4150) is an international, peer-reviewed journal devoted to pure and applied chemistry. AJRC publishes Original Research Articles, Short Communications, Review Articles in all aspects of chemistry. Topics covered including the traditional areas of analytical, inorganic, organic, biochemistry, forensic, physical-theoretical chemistry as well as newer interdisciplinary areas such as agriculture, materials science, computational, medicine, spectroscopy, polymers, supramolecular, surface, chemical physics, biological, medicinal/ drugs, environmental and pharmaceutical chemistry.
The journal is published quarterly every year in last week of March, June, September and December. From January 2011, is monthly and shall be published every year in last week of Month.    
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