ISSN

0974-4150 (Online)
0974-4169 (Print)


Author(s): T. Palanisamy, P. Rajkumar, K. Subramani

Email(s): drprajkumar2014@gmail.com

DOI: 10.5958/0974-4150.2016.00075.4   

Address: T. Palanisamy1, P. Rajkumar2 and K. Subramani3
1PG Department of Chemistry, H.H. The Rajah’s College (Affiliated to Bharathidasan University, Tiruchirapalli), Pudukkotai- 622001, Tamilnadu, India.
2Department of Chemistry, Priyadarshini Engineering College (Affiliated to Anna University, Chennai) Vaniyambadi-635751, Vellore District, Tamilnadu, India.
3PG & Research Department of Chemistry, Islamiah College (Affiliated to Thiruvalluvar University, Vellore), Vaniyambadi-635752, Vellore District, Tamilnadu, India.
*Corresponding Author

Published In:   Volume - 9,      Issue - 11,     Year - 2016


ABSTRACT:
The oxidation of pentaamminecobalt(III) complexes of a-hydroxy acids and by Manganese(III) Perchlorate (Mn(III)(ClO4)3) in micellar medium yielding nearly 100% of carbonyl compounds and 100% Co(II) are ultimate products. In this reaction the rate of oxidation shows first order kinetics each in [Co(III)] and [Mn(III)(ClO4)3]. The unbound a-hydroxy acids yield about 100% of carbonyl compounds in presence of micelles. The rate of oxidation of Co(III) complexes of both bound and unbound a- hydroxy acids are enhanced more in the presence of cationic micelle Cetyltrimethylammonium bromide (CTAB), when compared to the anionic micelle of Sodium laurylsulphate (NaLS). The 1 mole of cobalt(III) complexes of a-hydroxy acids reacts with nearly 0.5 mole of Manganese(III) Perchlorate, similarly 1 mole of a-hydroxy acids reacts with nearly 1 mole of Manganese(III) Perchlorate. The reaction goes by free radical mechanism was proved by acrylonitrile polymerization. The appropriate methodology has been inducted.


Cite this article:
T. Palanisamy, P. Rajkumar, K. Subramani. Kinetics of oxidation of Pentaamminecobalt (III) complexes of α-hydroxy acids By Mn(III)Perchlorate in Micellar Medium. Asian J. Research Chem. 2016; 9(11): 553-560. doi: 10.5958/0974-4150.2016.00075.4

Cite(Electronic):
T. Palanisamy, P. Rajkumar, K. Subramani. Kinetics of oxidation of Pentaamminecobalt (III) complexes of α-hydroxy acids By Mn(III)Perchlorate in Micellar Medium. Asian J. Research Chem. 2016; 9(11): 553-560. doi: 10.5958/0974-4150.2016.00075.4   Available on: https://www.ajrconline.org/AbstractView.aspx?PID=2016-9-11-1


Recomonded Articles:

Author(s): Syed Tasleem Hussain, Gul Abad Khan, Muhammad Shabeer

DOI:         Access: Open Access Read More

Author(s): Bhavna V. Mohite

DOI:         Access: Open Access Read More

Author(s): Prathima Patil, S.P. Sethy, T. Sameena, K. Shailaja

DOI:         Access: Open Access Read More

Author(s): Gullipilli Sandhya, R. Ravichandra Babu

DOI: 10.5958/0974-4150.2018.00115.3         Access: Open Access Read More

Author(s): Mukesh K. Nagar, Karishma R. Waghmare, P.N. Dhabale, Pradeep D. Chanekar, Suresh Bhatia

DOI:         Access: Open Access Read More

Author(s): Kishu Tripathi

DOI:         Access: Open Access Read More

Author(s): Suha K. Al-Mosawi, Hanan A. Al-Hazam, Abbas F. Abbas

DOI: 10.5958/0974-4150.2019.00031.2         Access: Open Access Read More

Author(s): Kateryna Taran, Ayaou Abderrahim, Vera Kravchenko, Olena Novosel, Svitlana Taran

DOI: 10.5958/0974-4150.2020.00034.6         Access: Open Access Read More

Author(s): Ravi N. Patel, Urviben Y. Patel, Kiran M. Patel, Jimit S. Patel, Ankit D. Patel, Dhrubo Jyoti Sen

DOI:         Access: Open Access Read More

Author(s): Vikram R. Jadhav

DOI: 10.5958/0974-4150.2020.00043.7         Access: Open Access Read More

Author(s): P. Valentina, K. Ilango, Deepak Jain, Prerna Shukla

DOI:         Access: Open Access Read More

Author(s): Mukund Nagarnaik, Arun Sarjoshi, Ajay Bodkhe, Bhupendra Khanal, Mayuri Pise, Girish Pandya

DOI: 10.5958/0974-4150.2015.00102.9         Access: Open Access Read More

Author(s): Merlin NJ Parthasarathy V, Manavalan R, Devi P, Meera R

DOI:         Access: Open Access Read More

Author(s): Arun Kumar, Vinita Gupta, Sanchita Singh, Y.K. Gupta

DOI: 10.5958/0974-4150.2017.00038.4         Access: Open Access Read More

Asian Journal of Research in Chemistry (AJRC) is an international, peer-reviewed journal devoted to pure and applied chemistry..... Read more >>>

RNI: Not Available                     
DOI: 10.5958/0974-4150 

Popular Articles


Recent Articles




Tags